The wastewater originated from any pre-treatment
(screening, primary sedimentation, grit removal,
etc..) is conveyed into an aeration tank which is
oxygenated mainly for insufflation of air. Within the
biological reactor, occurs the process of demolition
organic substance by means of bacteria which transform
it into simple substances (CO2, H2O) and energy which
then use it to grow and multiply.
The bioflocculation is a formation of gelatinous
flakes of a few mm of organic material present in
suspension. The aggregation of these flocculi is
assisted by the surface electric charge of the organic
molecules many of which are colloidal in nature and by
the presence of filamentous bacterial forms that
constitute a real inner armature on which depends the
cohesion of the flocculo. The bacterial forms present
are varied and selected from time to time and this
depends on the type of waste and global conditions
present in the tank; The active biomass in the
flocculo varies from 10 to 40% on the total of dry
matter. The flocculi if well-formed settle out and go
to form the so-called activated sludge, which settles
to the bottom and is placed in recirculation allowing
a progressive degradation of the organic substance
present in it.
At the exit from the oxidation tank the slurry is
introduced into the final sedimentation tank, in which
is obtained the separation of flocs from the purified
liquid part that is sent to potential tertiary
treatments (mainly filtration, disinfection) to be
identified in relation to the final delivery.
The most recent plant solutions also provide the
degradation of other nutrients (N and P).
The nitrogen is found in the sewage, mainly in the
form of ammonia: initially combined in molecules of
various complex organic substances, which are key
components of the cells of living organisms; the
transformation occurs by oxidation by biological means
and degradation of these substances, with consequent
solubilization into ammonia. The ammonia nitrogen is
subsequently oxidized, always for biological pathway,
to "nitrites" and further oxidized to
"nitrate", according to the following
simplified scheme:
C5H7O2N (organic
substances) +O2
--> NH3 (ammonia) + CO2 +
H2O NH3 (ammonia) + O2
--> NO2 - (nitrites) + H2O
NO2 (nitrites) + O2
--> NO3 - (nitrates)
These reactions occur in the oxidation basin by
specific strains of bacteria (Nitroso monas and
Nitrobacter) using the dissolved oxygen available in
the tank, introduced by means of a suitable system.
In the aerobic nitrogen transformation process we are
witnessing the conversion of the same from the reduced
form of ammonia nitrogen to the oxidized form of
nitrate nitrogen. The latter may be present in the
final effluent in a limited concentration and
therefore will have to undergo further processing.
The purpose is a step of denitrification in the anoxic
tank, in which numerous specialized bacterial strains
fix the oxygen present in the molecule of the nitrates
by using it for endogenous needs about the
metabolization of the organic substances; In fact,
these strains (heterotrophic) are facultative aerobes,
that is, if the surrounding environment there is the
presence of dissolved oxygen using it directly, while
in case of anoxia can use the oxygen present in the
nitrate.
This phase, with the aim of accelerating the reaction
kinetics and consequently the necessary volumes, is
usually carried out upstream of the compartment
oxidation-nitrification, and for this reason is
defined pre-denitrification.
The control of phosphorus discharged from municipal
and industrial wastewater treatment plants is a key
factor in the prevention of eutrophication of surface
waters.
The municipal waste waters can contain from 5 to 20 mg
/ l of total phosphorus, of which 1-5 mg / L are
organic and the remainder is inorganic.
The removal of phosphates is currently used mainly by
chemical precipitation with the addition of a
coagulant, in which the chemicals are fed directly
into the aeration tank or before it.
The most commonly used multivalent metal ions are iron
and aluminum.
The continuous recirculation of the sludge, together
with the adsorption processes and
coagulation-flocculation due to activated sludge,
allow a reduction in chemical consumption.
Ultimately the result that is obtained with an
activated sludge system is the elimination of the
biodegradable organic matter by means of
transformation into inert material and in a muddy
concentrated solution of the organic substance which
must be subjected to further treatment before final
disposal.
The plant scheme provides for:
- A pretreatment section (if any);
- A denitrification tank;
-
A nitrification tank and bio-oxidation of carbon;
-
A recirculation circuit (sludge and aerated
mixture) and a removal system of excess biomass;
- Adequate mixing and aeration systems;
-
A sub-fund for the separation of the sludge from
the waters "purified".
Applications
- Domestic and urban wastewater treatment;
-
Industrial waste water treatment:
- Agro-food industries;
- Paper industries;
- Textile industries;
- Tanneries;
- Chemical and pharmaceutical industries;
- Petroleum and petrochemical industries;
- Metallurgical and mining industries;
- Agricolture animal husbandry.